Information card for entry 7015950

Structure parameters

• Chemical name: fac-tricarbonyl(bis(N-(2-(dimethylstibanyl)benzyl))-methanamine)manganese(I) trifluoromethanesulfonate
• Formula: C23 H27 F3 Mn N O6 S Sb2
• Calculated formula: C23 H27 F3 Mn N O6 S Sb2
• SMILES: [Mn]12([Sb](C)(C)c3ccccc3C[N]2(C)Cc2ccccc2[Sb]1(C)C)(C#[O])(C#[O])C#[O].S(=O)(=O)([O-])C(F)(F)F
• Title of publication: Hybrid dibismuthines and distibines as ligands towards transition metal carbonyls.
• Authors of publication: Benjamin, Sophie L.; Levason, William; Reid, Gillian; Rogers, Michael C.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 24
• Pages of publication: 6565 - 6574
• a: 11.244 ± 0.0015 Å
• b: 14.737 ± 0.002 Å
• c: 17.721 ± 0.003 Å
• α: 90°
• β: 107.168 ± 0.01°
• γ: 90°
• Cell volume: 2805.6 ± 0.7 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0888
• Residual factor for significantly intense reflections: 0.0616
• Weighted residual factors for significantly intense reflections: 0.1121
• Weighted residual factors for all reflections included in the refinement: 0.1259
• Goodness-of-fit parameter for all reflections included in the refinement: 1.081
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No