Information card for entry 7016125

Structure parameters

• Formula: C74 H72 Ag2 Cl2 N22 O8 P2 S2
• Calculated formula: C74 H72 Ag2 Cl2 N22 O8 P2 S2
• SMILES: CN1[N]2=Cc3ccc4ccccc4[n]3[Ag]3452[N](N(C)P2(N(C)[N]6=Cc7ccc8ccccc8[n]7[Ag]786([N](N(C)P1(N(C)/N=C/c1nc6ccccc6cc1)=[S]48)=Cc1[n]7c4ccccc4cc1)[S]5=2)N(C)/N=C/c1nc2ccccc2cc1)=Cc1[n]3c2ccccc2cc1.[O-]Cl(=O)(=O)=O.C(#N)C.C(#N)C.[O-]Cl(=O)(=O)=O.C(#N)C.C(#N)C
• Title of publication: Assembly of a dinuclear silver complex containing an Ag(2)S(2) motif from a phosphorus-supported trishydrazone ligand. P[double bond, length as m-dash]S→Ag(I) coordination.
• Authors of publication: Chandrasekhar, Vadapalli; Pandey, Mrituanjay D.; Gopal, Kandasamy; Azhakar, Ramachandran
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 31
• Pages of publication: 7873 - 7878
• a: 10.753 ± 0.005 Å
• b: 12.954 ± 0.005 Å
• c: 15.432 ± 0.005 Å
• α: 80.692 ± 0.005°
• β: 85.963 ± 0.005°
• γ: 71.044 ± 0.005°
• Cell volume: 2005.9 ± 1.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0938
• Residual factor for significantly intense reflections: 0.0683
• Weighted residual factors for significantly intense reflections: 0.1789
• Weighted residual factors for all reflections included in the refinement: 0.2312
• Goodness-of-fit parameter for all reflections included in the refinement: 1.082
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No