Information card for entry 7016723

Structure parameters

• Formula: C18 H30 F2 N P
• Calculated formula: C18 H30 F2 N P
• Title of publication: Donor-stabilised cations, phosphinamide anions, and unusual oxidative cyclisation products from halogenated phosphoranimines and phosphinimines with a bulky 2,4,6-tri-tert-butylphenyl substituent at nitrogen.
• Authors of publication: Huynh, Keith; Chun, Cindy P.; Lough, Alan J.; Manners, Ian
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 40
• Pages of publication: 10576 - 10584
• a: 19.0219 ± 0.0007 Å
• b: 15.6776 ± 0.0008 Å
• c: 6.1422 ± 0.0003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1831.71 ± 0.15 ų
• Cell temperature: 150 ± 1 K
• Ambient diffraction temperature: 150 ± 1 K
• Number of distinct elements: 5
• Space group number: 62
• Hermann-Mauguin space group symbol: P n m a
• Hall space group symbol: -P 2ac 2n
• Residual factor for all reflections: 0.0713
• Residual factor for significantly intense reflections: 0.0472
• Weighted residual factors for significantly intense reflections: 0.1141
• Weighted residual factors for all reflections included in the refinement: 0.1288
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No