Information card for entry 7017907

Structure parameters

• Formula: C72 H50 Cl2 N10 O8 Os
• Calculated formula: C72 H50 Cl2 N10 O8 Os
• SMILES: c1cccc2c3cc(c4ccc(cc4)c4nc(c([nH]4)c4ccccc4)c4ccccc4)cc4[n]3[Os]35([n]12)([n]1c4cccc1)[n]1ccccc1c1cc(cc([n]31)c1[n]5cccc1)c1ccc(cc1)c1nc(c([nH]1)c1ccccc1)c1ccccc1.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• Title of publication: Luminescent bis-tridentate ruthenium(ii) and osmium(ii) complexes based on terpyridyl-imidazole ligand: synthesis, structural characterization, photophysical, electrochemical, and solvent dependence studies.
• Authors of publication: Bhaumik, Chanchal; Das, Shyamal; Maity, Dinesh; Baitalik, Sujoy
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 8
• Pages of publication: 2427 - 2438
• a: 36.393 ± 0.007 Å
• b: 37.524 ± 0.012 Å
• c: 23.564 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 32179 ± 14 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 6
• Space group number: 70
• Hermann-Mauguin space group symbol: F d d d :2
• Hall space group symbol: -F 2uv 2vw
• Residual factor for all reflections: 0.0895
• Residual factor for significantly intense reflections: 0.0509
• Weighted residual factors for significantly intense reflections: 0.1253
• Weighted residual factors for all reflections included in the refinement: 0.1351
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No