Information card for entry 7018316

Structure parameters

• Formula: C54 H44 Au2 F6 O6 P4 S2
• Calculated formula: C54 H44 Au2 F6 O6 P4 S2
• SMILES: FC(F)(F)S(=O)(=O)[O-].[Au]([P](c1ccccc1)(c1ccccc1)/C=C\[P]([Au]1)(c2ccccc2)c2ccccc2)[P](/C=C\[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.FC(F)(F)S(=O)(=O)[O-]
• Title of publication: Synthesis and structures of cyclic gold complexes containing diphosphine ligands and luminescent properties of the high nuclearity species.
• Authors of publication: Bhargava, Suresh; Kitadai, Kunihiko; Masashi, Takahashi; Drumm, Daniel W.; Russo, Salvy P.; Yam, Vivian Wing-Wah; Lee, Terence Kwok-Ming; Wagler, Jörg; Mirzadeh, Nedaossadat
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 16
• Pages of publication: 4789 - 4798
• a: 10.8043 ± 0.0006 Å
• b: 10.9164 ± 0.0006 Å
• c: 11.7847 ± 0.0006 Å
• α: 76.473 ± 0.001°
• β: 82.956 ± 0.001°
• γ: 73.34 ± 0.001°
• Cell volume: 1292.34 ± 0.12 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0221
• Residual factor for significantly intense reflections: 0.0217
• Weighted residual factors for significantly intense reflections: 0.0583
• Weighted residual factors for all reflections included in the refinement: 0.0586
• Goodness-of-fit parameter for all reflections included in the refinement: 1.06
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No