Information card for entry 7018909

Structure parameters

• Chemical name: bis((μ2-3,5-bis(trifluoromethyl)pyrazolato)-bis(trimethylphosphine)-rhodium(i))
• Formula: C22 H38 F12 N4 P4 Rh2
• Calculated formula: C22 H38 F12 N4 P4 Rh2
• SMILES: [Rh]([P](C)(C)C)([P](C)(C)C)([n]1n([Rh]2([P](C)(C)C)[P](C)(C)C)c(C(F)(F)F)cc1C(F)(F)F)[n]1n2c(C(F)(F)F)cc1C(F)(F)F
• Title of publication: Rhodium pyrazolate complexes as potential CVD precursors.
• Authors of publication: Rivers, Joseph H.; Depue Anderson, Lauren J.; Starr, Cotton M. N.; Jones, Richard A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 17
• Pages of publication: 5401 - 5408
• a: 11.0386 ± 0.0003 Å
• b: 15.8199 ± 0.0004 Å
• c: 39.769 ± 0.0005 Å
• α: 90°
• β: 93.99 ± 0.02°
• γ: 90°
• Cell volume: 6928 ± 0.3 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1108
• Residual factor for significantly intense reflections: 0.0733
• Weighted residual factors for significantly intense reflections: 0.2079
• Weighted residual factors for all reflections included in the refinement: 0.2219
• Goodness-of-fit parameter for all reflections included in the refinement: 1.855
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No