Information card for entry 7018926

Structure parameters

• Formula: Cu2 Ge2 H74 Mo18 Na8 O101
• Calculated formula: Cu2 Ge2 Mo18 Na8 O101
• SMILES: O=[Mo]1234[O]5[Mo]67([O]84[Ge]49[O]%10%11[Mo]%12%13%14([O]2[Mo]25([O]7[Mo]%11([O]%142)(O[Mo]2%10(O%12)(O[Mo]5(O[Mo](O3)(O[Mo]8(O1)(O6)(=O)=[O][Cu]13[O]9[Cu]6([O]=2)[O]=[Mo]278(O[Mo]9%10%11(=O)[O]%12[Mo]%14([O]2%11[Ge]2([O]%11%15[Mo]%16%17%18([O]9[Mo]9%12([O]%14[Mo]%15([O]%189)(O[Mo]%11(O%16)(O[Mo]9(O[Mo](O%10)(O8)(=O)(=O)[O]29)(=O)(=O)O%17)(=O)=[O]1)(=O)=O)(=O)=O)=O)[O]36)(=O)(O7)=O)=O)(=O)(=O)[O]45)(=O)(O%13)=O)=O)(=O)=O)(=O)=O)=O)(=O)=O.[Na+].O.O.O.O.[Na+].O.[Na+].O.[Na+].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Na+].O.[Na+].O.[Na+].O.O.O.O.[Na+].O.O.O.O.O.O.O
• Title of publication: Four di-Cu(II)-substituted sandwich-type germanomolybdates obtained under different reaction conditions: from zero-dimensional to two-dimensional structure.
• Authors of publication: Li, Suzhi; Guo, Yuan Yuan; Zhang, Dongdi; Ma, Pengtao; Qiu, Xiaoyang; Wang, Jingping; Niu, Jingyang
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 17
• Pages of publication: 5235 - 5240
• a: 12.482 ± 0.007 Å
• b: 12.791 ± 0.008 Å
• c: 17.272 ± 0.015 Å
• α: 101.422 ± 0.014°
• β: 98.402 ± 0.013°
• γ: 115.982 ± 0.01°
• Cell volume: 2343 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0671
• Residual factor for significantly intense reflections: 0.0538
• Weighted residual factors for significantly intense reflections: 0.1284
• Weighted residual factors for all reflections included in the refinement: 0.1323
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No