Information card for entry 7019139

Structure parameters

• Common name: (N,N?-bis(4-azido-2,6-diisopropylphenyl)imidazol-2- ylidene)chlorosilver(i)
• Formula: C28 H36 Ag Cl3 N8
• Calculated formula: C28 H36 Ag Cl3 N8
• SMILES: C1(N(C=CN1c1c(C(C)C)cc(cc1C(C)C)N=N#N)c1c(cc(cc1C(C)C)N=N#N)C(C)C)=[Ag]Cl.C(Cl)Cl
• Title of publication: Access to functionalised silver(i) and gold(i) N-heterocyclic carbenes by [2 + 3] dipolar cycloadditions.
• Authors of publication: Hospital, Audrey; Gibard, Clémentine; Gaulier, Christelle; Nauton, Lionel; Théry, Vincent; El-Ghozzi, Malika; Avignant, Daniel; Cisnetti, Federico; Gautier, Arnaud
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 22
• Pages of publication: 6803 - 6812
• a: 10.0772 ± 0.0003 Å
• b: 15.3419 ± 0.0005 Å
• c: 21.5215 ± 0.0008 Å
• α: 90°
• β: 92.164 ± 0.001°
• γ: 90°
• Cell volume: 3324.92 ± 0.19 ų
• Cell temperature: 293 K
• Ambient diffraction temperature: 293 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0651
• Residual factor for significantly intense reflections: 0.0425
• Weighted residual factors for all reflections: 0.0883
• Weighted residual factors for significantly intense reflections: 0.049
• Weighted residual factors for all reflections included in the refinement: 0.0473
• Goodness-of-fit parameter for all reflections included in the refinement: 0.8432
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No