Information card for entry 7020551

Structure parameters

• Formula: C32 H41 F3 O5 P3 Rh S
• Calculated formula: C32 H41 F3 O5 P3 Rh S
• SMILES: [Rh]12([P](c3ccccc3P(c3ccccc3)(c3ccccc3[P]1(C(C)C)C(C)C)=[O]2)(C(C)C)C(C)C)C#[O].S(=O)(=O)([O-])C(F)(F)F
• Title of publication: Coordination of a diphosphine-phosphine oxide to Au, Ag and Rh: when polyfunctionality rhymes with versatility.
• Authors of publication: Derrah, Eric J.; Martin, Carmen; Ladeira, Sonia; Miqueu, Karinne; Bouhadir, Ghenwa; Bourissou, Didier
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2012
• Journal volume: 41
• Journal issue: 47
• Pages of publication: 14274 - 14280
• a: 8.1191 ± 0.0005 Å
• b: 19.9268 ± 0.0012 Å
• c: 23.3037 ± 0.0015 Å
• α: 68.072 ± 0.003°
• β: 85.812 ± 0.003°
• γ: 85.295 ± 0.003°
• Cell volume: 3482 ± 0.4 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1047
• Residual factor for significantly intense reflections: 0.0602
• Weighted residual factors for significantly intense reflections: 0.1232
• Weighted residual factors for all reflections included in the refinement: 0.1396
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No