Synthesis of new bulky bis(pyrazolyl)methane carboxylate (heteroscorpionate) ligands and their complexes with iron, manganese and nickel.
Authors of publication
Jones, Michael W.; Baldwin, Jack E.; Cowley, Andrew R.; Dilworth, Jonathan R.; Karpov, Alexei; Smiljanic, Nicolas; Thompson, Amber L.; Adlington, Robert M.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2012
Journal volume
41
Journal issue
46
Pages of publication
14068 - 14086
a
12.5703 ± 0.0005 Å
b
13.0224 ± 0.0005 Å
c
14.5998 ± 0.0006 Å
α
80.272 ± 0.003°
β
66.147 ± 0.004°
γ
85.055 ± 0.003°
Cell volume
2153.94 ± 0.16 Å3
Cell temperature
150 K
Ambient diffraction temperature
150 K
Number of distinct elements
6
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0544
Residual factor for significantly intense reflections
0.0456
Weighted residual factors for all reflections
0.1234
Weighted residual factors for significantly intense reflections
0.1172
Weighted residual factors for all reflections included in the refinement
0.1233
Goodness-of-fit parameter for all reflections included in the refinement
