Synthesis of new bulky bis(pyrazolyl)methane carboxylate (heteroscorpionate) ligands and their complexes with iron, manganese and nickel.
Authors of publication
Jones, Michael W.; Baldwin, Jack E.; Cowley, Andrew R.; Dilworth, Jonathan R.; Karpov, Alexei; Smiljanic, Nicolas; Thompson, Amber L.; Adlington, Robert M.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2012
Journal volume
41
Journal issue
46
Pages of publication
14068 - 14086
a
14.1426 ± 0.0002 Å
b
22.544 ± 0.0004 Å
c
11.9542 ± 0.0002 Å
α
90°
β
90.603 ± 0.001°
γ
90°
Cell volume
3811.16 ± 0.11 Å3
Cell temperature
150 K
Ambient diffraction temperature
150 K
Number of distinct elements
4
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.0932
Residual factor for significantly intense reflections
0.0551
Weighted residual factors for all reflections
0.1651
Weighted residual factors for significantly intense reflections
0.1284
Weighted residual factors for all reflections included in the refinement
0.1651
Goodness-of-fit parameter for all reflections included in the refinement
