Information card for entry 7020745

Structure parameters

• Formula: C25 H44 B F3 N2 O3 P2 Pt S
• Calculated formula: C25 H44 B F3 N2 O3 P2 Pt S
• SMILES: [Pt]12([P](CN3B2N(c2c3cccc2)C[P]1(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C)OS(=O)(=O)C(F)(F)F
• Title of publication: Platinum complexes bearing a boron-based PBP pincer ligand: synthesis, structure, and application as a catalyst for hydrosilylation of 1-decene.
• Authors of publication: Ogawa, Hayato; Yamashita, Makoto
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 3
• Pages of publication: 625 - 629
• a: 8.0942 ± 0.0018 Å
• b: 17.423 ± 0.004 Å
• c: 21.755 ± 0.005 Å
• α: 90°
• β: 93.554 ± 0.004°
• γ: 90°
• Cell volume: 3062.1 ± 1.2 ų
• Cell temperature: 93.15 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0221
• Residual factor for significantly intense reflections: 0.0191
• Weighted residual factors for significantly intense reflections: 0.0435
• Weighted residual factors for all reflections included in the refinement: 0.0448
• Goodness-of-fit parameter for all reflections included in the refinement: 1.064
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No