Interplay of bite angle and cone angle effects. A comparison between o-C6H4(CH2PR2)(PR'2) and o-C6H4(CH2PR2)(CH2PR'2) as ligands for Pd-catalysed ethene hydromethoxycarbonylation.
Authors of publication
Fanjul, Tamara; Eastham, Graham; Floure, Joelle; Forrest, Sebastian J. K.; Haddow, Mairi F.; Hamilton, Alex; Pringle, Paul G.; Orpen, A. Guy; Waugh, Mark
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2013
Journal volume
42
Journal issue
1
Pages of publication
100 - 115
a
11.4182 ± 0.0001 Å
b
15.7441 ± 0.0001 Å
c
15.0578 ± 0.0001 Å
α
90°
β
103.53 ± 0.0008°
γ
90°
Cell volume
2631.8 ± 0.03 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.036
Residual factor for significantly intense reflections
0.0254
Weighted residual factors for significantly intense reflections
0.0518
Weighted residual factors for all reflections included in the refinement
0.0592
Goodness-of-fit parameter for all reflections included in the refinement
