Information card for entry 7021700

Structure parameters

• Chemical name: Osmium(0)(eta4-1,5-cyclooctadiene)(eta6-1,3,5,7-cyclooctatetraene)
• Formula: C16 H20 Os
• Calculated formula: C16 H20 Os
• SMILES: [Os]12345678([CH]9=[CH]1CC[CH]2=[CH]3CC9)[CH]1C=C[CH]8=[CH]7[CH]6=[CH]5[CH]4=1
• Title of publication: Narrowly dispersed silica supported osmium nanoparticles prepared by an organometallic approach: H2 and CO adsorption stoichiometry and hydrogenolysis catalytic activity.
• Authors of publication: Low, Jia En; Foelske-Schmitz, Annette; Krumeich, Frank; Wörle, Michael; Baudouin, David; Rascón, Fernando; Copéret, Christophe
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 35
• Pages of publication: 12620 - 12625
• a: 12.293 ± 0.002 Å
• b: 8.9556 ± 0.0016 Å
• c: 13.02 ± 0.002 Å
• α: 90°
• β: 115.75 ± 0.004°
• γ: 90°
• Cell volume: 1291 ± 0.4 ų
• Cell temperature: 233 ± 2 K
• Ambient diffraction temperature: 233.15 K
• Number of distinct elements: 3
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0354
• Residual factor for significantly intense reflections: 0.0195
• Weighted residual factors for significantly intense reflections: 0.0385
• Weighted residual factors for all reflections included in the refinement: 0.0424
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Diffraction radiation X-ray symbol: K-L~3~
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No