Synthesis and structures of calcium and strontium 2,4-di-tert-butylphenolates and their reactivity towards the amine co-initiated ring-opening polymerisation of rac-lactide.
Authors of publication
Clark, Lawrence; Deacon, Glen B.; Forsyth, Craig M.; Junk, Peter C.; Mountford, Philip; Townley, Josh P.; Wang, Jun
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2013
Journal volume
42
Journal issue
25
Pages of publication
9294 - 9312
a
24.136 ± 0.003 Å
b
13.9781 ± 0.0014 Å
c
25.508 ± 0.004 Å
α
90°
β
112.206 ± 0.004°
γ
90°
Cell volume
7967.5 ± 1.8 Å3
Cell temperature
123 ± 1 K
Ambient diffraction temperature
123 ± 1 K
Number of distinct elements
4
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.1104
Residual factor for significantly intense reflections
0.0719
Weighted residual factors for significantly intense reflections
0.176
Weighted residual factors for all reflections included in the refinement
0.1994
Goodness-of-fit parameter for all reflections included in the refinement
