Information card for entry 7024067

Structure parameters

• Chemical name: Uranium(V) tris(hexamethyldisilazide) bis(azide)
• Formula: C24 H68 N9 Si6 U
• Calculated formula: C24 H68 N9 Si6 U
• SMILES: C[Si](N([U](N=N#N)(N([Si](C)(C)C)[Si](C)(C)C)(N=N#N)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C)(C)C.C(CC)CCC
• Title of publication: U(IV) and U(V) azide complexes supported by amide or aryloxide ligands.
• Authors of publication: Fortier, Skye; Wu, Guang; Hayton, Trevor W.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 2
• Pages of publication: 352 - 354
• a: 18.767 ± 0.001 Å
• b: 14.6497 ± 0.0008 Å
• c: 16.8791 ± 0.0009 Å
• α: 90°
• β: 111.295 ± 0.002°
• γ: 90°
• Cell volume: 4323.7 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0305
• Residual factor for significantly intense reflections: 0.0243
• Weighted residual factors for significantly intense reflections: 0.0561
• Weighted residual factors for all reflections included in the refinement: 0.0581
• Goodness-of-fit parameter for all reflections included in the refinement: 1.011
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No