Information card for entry 7024197

Structure parameters

• Chemical name: [Pt(PP3)2](NO3)2.2CHCl3
• Formula: C86 H84 Cl6 N2 O6 P8 Pt
• Calculated formula: C86 H84 Cl6 N2 O6 P8 Pt
• SMILES: C(CP(c1ccccc1)c1ccccc1)[P]1([Pt]2([P](CC[P]2(c2ccccc2)c2ccccc2)(CCP(c2ccccc2)c2ccccc2)CCP(c2ccccc2)c2ccccc2)[P](CC1)(c1ccccc1)c1ccccc1)CCP(c1ccccc1)c1ccccc1.O=N(=O)[O-].ClC(Cl)Cl.O=N(=O)[O-].ClC(Cl)Cl
• Title of publication: Tripodal polyphosphine ligands as inductors of chelate ring-opening processes in mononuclear palladium(II) and platinum(II) compounds. The X-ray crystal structure of two derivatives containing dangling phosphorus.
• Authors of publication: Fernández-Anca, Damián; García-Seijo, M Inés; García-Fernández, M Esther
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 9
• Pages of publication: 2327 - 2336
• a: 12.953 ± 0.0018 Å
• b: 13.2829 ± 0.0018 Å
• c: 15.424 ± 0.002 Å
• α: 103.192 ± 0.002°
• β: 105.354 ± 0.002°
• γ: 112.81 ± 0.002°
• Cell volume: 2189.4 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0602
• Residual factor for significantly intense reflections: 0.0391
• Weighted residual factors for significantly intense reflections: 0.0674
• Weighted residual factors for all reflections included in the refinement: 0.0729
• Goodness-of-fit parameter for all reflections included in the refinement: 0.878
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No