New achiral and chiral NNE heteroscorpionate ligands. Synthesis of homoleptic lithium complexes as well as halide and alkyl scandium and yttrium complexes.
Authors of publication
Otero, Antonio; Lara-Sánchez, Agustín; Fernández-Baeza, Juan; Martínez-Caballero, Emilia; Márquez-Segovia, Isabel; Alonso-Moreno, Carlos; Sánchez-Barba, Luis F; Rodríguez, Ana M; López-Solera, Isabel
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2010
Journal volume
39
Journal issue
3
Pages of publication
930 - 940
a
12.048 ± 0.002 Å
b
11.477 ± 0.002 Å
c
13.263 ± 0.005 Å
α
90°
β
90.43 ± 0.03°
γ
90°
Cell volume
1833.9 ± 0.8 Å3
Cell temperature
180 ± 2 K
Ambient diffraction temperature
180 ± 2 K
Number of distinct elements
4
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.1916
Residual factor for significantly intense reflections
0.0561
Weighted residual factors for significantly intense reflections
0.1301
Weighted residual factors for all reflections included in the refinement
0.1905
Goodness-of-fit parameter for all reflections included in the refinement
