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Information card for entry 7024335
Preview
Coordinates | 7024335.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C43 H22 O15 P2 Ru6 |
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Calculated formula | C43 H22 O15 P2 Ru6 |
SMILES | [Ru]123456([Ru]789%10([Ru]%11%12%13([Ru]%14%15%161([Ru]27%11([P]([C]15=[C]4%15C(=O)CC1=O)(c1ccccc1)c1ccccc1)([C]6%10%13%16[Ru]38%12%14([P]9(c1ccccc1)c1ccccc1)(C#[O])C#[O])(C#[O])C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O])(C#[O])C#[O])(C#[O])C#[O] |
Title of publication | Ligand substitution behavior of Ru(6)(mu(6)-C)(CO)(17) with unsaturated diphosphines: facile capping of a polyhedral face and photochemically promoted P-C bond cleavage in the cluster Ru(6)(mu(6)-C)(CO)(14)(mu(3)-bpcd). |
Authors of publication | Kandala, Srikanth; Hammons, Casey; Watson, William H.; Wang, Xiaoping; Richmond, Michael G. |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2010 |
Journal volume | 39 |
Journal issue | 6 |
Pages of publication | 1620 - 1629 |
a | 10.9089 ± 0.0018 Å |
b | 16.326 ± 0.003 Å |
c | 27.66 ± 0.005 Å |
α | 103.363 ± 0.003° |
β | 97.888 ± 0.003° |
γ | 104.35 ± 0.003° |
Cell volume | 4543.3 ± 1.4 Å3 |
Cell temperature | 213 ± 2 K |
Ambient diffraction temperature | 213 ± 2 K |
Number of distinct elements | 5 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0741 |
Residual factor for significantly intense reflections | 0.0416 |
Weighted residual factors for significantly intense reflections | 0.0898 |
Weighted residual factors for all reflections included in the refinement | 0.1065 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.901 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7024335.html
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Users of the data should acknowledge the original authors of the
structural data.