Information card for entry 7024864

Structure parameters

• Formula: C23 H34 N3 O5 P Si2 W
• Calculated formula: C23 H34 N3 O5 P Si2 W
• SMILES: C1(c2ccccc2)N(C(=N[P]1(C([Si](C)(C)C)[Si](C)(C)C)[W](C#[O])(C#[O])(C#[O])(C#[O])C#[O])N(C)C)C
• Title of publication: Novel access to azaphosphiridine complexes and first applications using Brønsted acid-induced ring expansion reactions.
• Authors of publication: Fankel, Stefan; Helten, Holger; von Frantzius, Gerd; Schnakenburg, Gregor; Daniels, Jörg; Chu, Victoria; Müller, Christina; Streubel, Rainer
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 14
• Pages of publication: 3472 - 3481
• a: 9.8089 ± 0.0004 Å
• b: 10.0809 ± 0.0005 Å
• c: 16.4987 ± 0.0009 Å
• α: 86.801 ± 0.002°
• β: 87.041 ± 0.003°
• γ: 66.682 ± 0.003°
• Cell volume: 1495.07 ± 0.13 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0471
• Residual factor for significantly intense reflections: 0.0319
• Weighted residual factors for significantly intense reflections: 0.0527
• Weighted residual factors for all reflections included in the refinement: 0.0561
• Goodness-of-fit parameter for all reflections included in the refinement: 0.839
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No