Information card for entry 7024973

Structure parameters

• Formula: C21 H33 B I2 N7 O Rh
• Calculated formula: C21 H25 B I2 N7 O Rh
• Title of publication: Heterolytic H2 activation by rhodium thiolato complexes bearing the hydrotris(pyrazolyl)borato ligand and application to catalytic hydrogenation under mild conditions.
• Authors of publication: Seino, Hidetake; Misumi, Yoshiyuki; Hojo, Yoshihiro; Mizobe, Yasushi
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 12
• Pages of publication: 3072 - 3082
• a: 7.9782 ± 0.0015 Å
• b: 13.431 ± 0.003 Å
• c: 26.285 ± 0.005 Å
• α: 90°
• β: 97.916 ± 0.003°
• γ: 90°
• Cell volume: 2789.7 ± 1 ų
• Cell temperature: 113.1 K
• Ambient diffraction temperature: 113.1 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.0337
• Weighted residual factors for all reflections included in the refinement: 0.1166
• Goodness-of-fit parameter for all reflections included in the refinement: 1.005
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No