A missing high-spin molecule in the family of cyanido-bridged heptanuclear heterometal complexes, [(LCuII)6FeIII(CN)6]3+, and its CoIII and CrIII analogues, accompanied in the crystal by a novel octameric water cluster
Authors of publication
Maxim, Catalin; Sorace, Lorenzo; Khuntia, Panchanana; Madalan, Augustin M.; Kravtsov, Victor; Lascialfari, Alessandro; Caneschi, Andrea; Journaux, Yves; Andruh, Marius
Journal of publication
Dalton Transactions
Year of publication
2010
Journal volume
39
Journal issue
20
Pages of publication
4838
a
17.546 ± 0.0011 Å
b
37.803 ± 0.0011 Å
c
9.994 ± 0.002 Å
α
90 ± 0.005°
β
90 ± 0.004°
γ
90 ± 0.005°
Cell volume
6628.9 ± 1.4 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
6
Space group number
43
Hermann-Mauguin space group symbol
F d d 2
Hall space group symbol
F 2 -2d
Residual factor for all reflections
0.0643
Residual factor for significantly intense reflections
0.044
Weighted residual factors for significantly intense reflections
0.1002
Weighted residual factors for all reflections included in the refinement
0.1055
Goodness-of-fit parameter for all reflections included in the refinement
