Information card for entry 7025026

Structure parameters

• Formula: C18 H19 Cl F6 N9 P Pt
• Calculated formula: C18 H19.5 Cl F6 N9 P Pt
• SMILES: [Pt]1(=C2N(C=CN2C)c2[n]1cccn2)(Cl)=C1N(C=CN1C)c1ncccn1.[P](F)(F)(F)(F)(F)[F-].N#CC
• Title of publication: Platinum(II) complexes with polydentate N-heterocyclic carbenes: synthesis, structural characterization and hydrosilylation catalysis.
• Authors of publication: Lu, Chunxin; Gu, Shaojin; Chen, Wanzhi; Qiu, Huayu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 17
• Pages of publication: 4198 - 4204
• a: 6.9251 ± 0.0008 Å
• b: 21.38 ± 0.02 Å
• c: 33.695 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4989 ± 5 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 7
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0945
• Residual factor for significantly intense reflections: 0.0731
• Weighted residual factors for significantly intense reflections: 0.1625
• Weighted residual factors for all reflections included in the refinement: 0.171
• Goodness-of-fit parameter for all reflections included in the refinement: 1.109
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No