Information card for entry 7025030

Structure parameters

• Formula: C38 H34 F12 N14 P2 Pt
• Calculated formula: C38 H34 F12 N14 P2 Pt
• SMILES: c1ccnc(c1)N1C2=[Pt]3(=C4N(C=CN4c4ncccc4)CN4C=3N(C=C4)c3ccccn3)=C3N(CN2C=C1)C=CN3c1ncccc1.[P](F)(F)(F)(F)(F)[F-].N#CC.[P](F)(F)(F)(F)(F)[F-].N#CC
• Title of publication: Platinum(II) complexes with polydentate N-heterocyclic carbenes: synthesis, structural characterization and hydrosilylation catalysis.
• Authors of publication: Lu, Chunxin; Gu, Shaojin; Chen, Wanzhi; Qiu, Huayu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 17
• Pages of publication: 4198 - 4204
• a: 8.4356 ± 0.0009 Å
• b: 11.5167 ± 0.0011 Å
• c: 12.5996 ± 0.0014 Å
• α: 107.89 ± 0.002°
• β: 102.804 ± 0.001°
• γ: 100.03 ± 0.001°
• Cell volume: 1096.5 ± 0.2 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0354
• Residual factor for significantly intense reflections: 0.0353
• Weighted residual factors for significantly intense reflections: 0.0901
• Weighted residual factors for all reflections included in the refinement: 0.0901
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No