Low-coordinate rare-earth complexes of the asymmetric 2,4-di-tert-butylphenolate ligand prepared by redox transmetallation/protolysis reactions, and their reactivity towards ring-opening polymerisation.
Authors of publication
Clark, Lawrence; Deacon, Glen B.; Forsyth, Craig M.; Junk, Peter C.; Mountford, Philip; Townley, Josh P.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2010
Journal volume
39
Journal issue
29
Pages of publication
6693 - 6704
a
24.1258 ± 0.0014 Å
b
9.3193 ± 0.0006 Å
c
27.4879 ± 0.0015 Å
α
90°
β
105.778 ± 0.002°
γ
90°
Cell volume
5947.4 ± 0.6 Å3
Cell temperature
123 ± 2 K
Ambient diffraction temperature
123 ± 2 K
Number of distinct elements
4
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.075
Residual factor for significantly intense reflections
0.0626
Weighted residual factors for significantly intense reflections
0.1288
Weighted residual factors for all reflections included in the refinement
0.1332
Goodness-of-fit parameter for all reflections included in the refinement
