Low-coordinate rare-earth complexes of the asymmetric 2,4-di-tert-butylphenolate ligand prepared by redox transmetallation/protolysis reactions, and their reactivity towards ring-opening polymerisation.
Authors of publication
Clark, Lawrence; Deacon, Glen B.; Forsyth, Craig M.; Junk, Peter C.; Mountford, Philip; Townley, Josh P.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2010
Journal volume
39
Journal issue
29
Pages of publication
6693 - 6704
a
11.6509 ± 0.0002 Å
b
14.0152 ± 0.0002 Å
c
14.7135 ± 0.0002 Å
α
72.387 ± 0.001°
β
82.619 ± 0.001°
γ
81.695 ± 0.001°
Cell volume
2256.75 ± 0.06 Å3
Cell temperature
123 ± 2 K
Ambient diffraction temperature
123 ± 2 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0365
Residual factor for significantly intense reflections
0.0319
Weighted residual factors for significantly intense reflections
0.0746
Weighted residual factors for all reflections included in the refinement
0.0771
Goodness-of-fit parameter for all reflections included in the refinement
