The gas-phase structure and some reactions of the bulky primary silane (Me(3)Si)(3)CSiH(3) and the solid-state structure of the bulky dialkyl disilane [(Me(3)Si)(3)CSiH(2)](2).
Authors of publication
Masters, Sarah L.; Rankin, David W. H.; Cordes, David B.; Bätz, Karin; Lickiss, Paul D.; Boag, Neil M.; Redhouse, Alan D.; Whittaker, Stephen M.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2010
Journal volume
39
Journal issue
39
Pages of publication
9353 - 9360
a
9.09 ± 0.004 Å
b
12.712 ± 0.004 Å
c
15.286 ± 0.005 Å
α
108.29 ± 0.03°
β
90.32 ± 0.03°
γ
91.49 ± 0.03°
Cell volume
1676.4 ± 1.1 Å3
Cell temperature
203 ± 2 K
Ambient diffraction temperature
203 ± 2 K
Number of distinct elements
3
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0649
Residual factor for significantly intense reflections
0.0455
Weighted residual factors for significantly intense reflections
0.1044
Weighted residual factors for all reflections included in the refinement
0.1121
Goodness-of-fit parameter for all reflections included in the refinement
