Information card for entry 7026027

Structure parameters

• Formula: C20 H34 P2 Rh Ta
• Calculated formula: C20 H34 P2 Rh Ta
• SMILES: [Ta]123456789([P]([Rh]%10([P]1(CC)CC)[CH2]=[CH2]%10)(CC)CC)([cH]1[cH]2[cH]3[cH]4[cH]51)[cH]1[cH]6[cH]7[cH]8[cH]91
• Title of publication: Phosphido-bridged Ta/Rh bimetallic complex: synthesis, structure, and catalytic hydrosilylation of acetophenone.
• Authors of publication: Findlay, Andrea E.; Leelasubcharoen, Somying; Kuzmina, Lyudmila G.; Howard, Judith A. K.; Nikonov, Georgii I.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 39
• Pages of publication: 9264 - 9269
• a: 9.4251 ± 0.0006 Å
• b: 9.8107 ± 0.0006 Å
• c: 13.4457 ± 0.0008 Å
• α: 69.198 ± 0.002°
• β: 72.757 ± 0.002°
• γ: 64.751 ± 0.002°
• Cell volume: 1035.64 ± 0.11 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0211
• Residual factor for significantly intense reflections: 0.0202
• Weighted residual factors for significantly intense reflections: 0.0518
• Weighted residual factors for all reflections included in the refinement: 0.0523
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No