Information card for entry 7026034

Structure parameters

• Formula: C73 H106 N6 O7 Si2 Zn
• Calculated formula: C73 H106 N6 O7 Si2 Zn
• SMILES: [Zn]12(O[Si]3(N(C(=C)C=C(N3c3c(cccc3C(C)C)C(C)C)C)c3c(cccc3C(C)C)C(C)C)OC(=[O]1)C)(O[Si]1(N(C(=C)C=C(N1c1c(cccc1C(C)C)C(C)C)C)c1c(cccc1C(C)C)C(C)C)OC(=[O]2)C)[n]1ccc(N(C)C)cc1.O(CC)CC
• Title of publication: Coordination of a Si[double bond, length as m-dash]O subunit to metals: complexes of donor-stabilized silanone featuring a terminal Si[double bond, length as m-dash]O→M coordination (M = Zn, Al).
• Authors of publication: Xiong, Yun; Yao, Shenglai; Driess, Matthias
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 39
• Pages of publication: 9282 - 9287
• a: 12.5933 ± 0.0003 Å
• b: 13.2139 ± 0.0004 Å
• c: 23.3919 ± 0.0006 Å
• α: 104.044 ± 0.002°
• β: 95.106 ± 0.002°
• γ: 101.459 ± 0.002°
• Cell volume: 3662.2 ± 0.18 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0877
• Residual factor for significantly intense reflections: 0.0604
• Weighted residual factors for significantly intense reflections: 0.1318
• Weighted residual factors for all reflections included in the refinement: 0.1435
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No