Information card for entry 7026250

Structure parameters

• Formula: C46.5 H54 B2 Cl3 F8 N2 P Rh2
• Calculated formula: C46.5 H54 B2 Cl3 F8 N2 P Rh2
• Title of publication: Rhodium and iridium complexes containing diphenyl-2-(3-methyl)indolylphosphine: synthesis, structure and application in the catalytic transfer hydrogenation of ketones.
• Authors of publication: Kuo, Yu-Ying; Haddow, Mairi F.; Pérez-Redondo, Adrián; Owen, Gareth R.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 27
• Pages of publication: 6239 - 6248
• a: 11.0623 ± 0.0004 Å
• b: 11.2983 ± 0.0004 Å
• c: 19.1151 ± 0.0007 Å
• α: 92.954 ± 0.002°
• β: 98.481 ± 0.002°
• γ: 99.342 ± 0.002°
• Cell volume: 2324.66 ± 0.15 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0675
• Residual factor for significantly intense reflections: 0.0464
• Weighted residual factors for significantly intense reflections: 0.1171
• Weighted residual factors for all reflections included in the refinement: 0.1302
• Goodness-of-fit parameter for all reflections included in the refinement: 1.065
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No