Information card for entry 7026503

Structure parameters

• Formula: C52 H61 F6 N8 O5.5 Os2 P S2
• Calculated formula: C52 H60.5 F6 N8 O5.25 Os2 P S2
• Title of publication: Formation of μ-dinitrogen (salen)osmium complexes via ligand-induced N···N coupling of (salen)osmium(VI) nitrides.
• Authors of publication: Man, Wai-Lun; Chen, Gui; Yiu, Shek-Man; Shek, Lam; Wong, Wai-Yeung; Wong, Wing-Tak; Lau, Tai-Chu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 46
• Pages of publication: 11163 - 11170
• a: 12.955 ± 0.001 Å
• b: 15.0689 ± 0.0012 Å
• c: 16.7304 ± 0.0013 Å
• α: 90.153 ± 0.001°
• β: 112.613 ± 0.001°
• γ: 103.882 ± 0.002°
• Cell volume: 2910.5 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0472
• Residual factor for significantly intense reflections: 0.0376
• Weighted residual factors for significantly intense reflections: 0.105
• Weighted residual factors for all reflections included in the refinement: 0.1134
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No