Information card for entry 7026505

Structure parameters

• Formula: C48 H50 F12 N8 O4 Os2 P2 S2
• Calculated formula: C48 H50 F12 N8 O4 Os2 P2 S2
• SMILES: c12ccccc1C=[N]1[Os]3([N]#[N][Os]456([N](=Cc7c(cccc7)O5)[C@H]5CCCC[C@@H]5[N]4=Cc4ccccc4O6)[n]4cscc4C)([n]4cscc4C)(O2)[N]([C@H]2[C@H]1CCCC2)=Cc1ccccc1O3.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Formation of μ-dinitrogen (salen)osmium complexes via ligand-induced N···N coupling of (salen)osmium(VI) nitrides.
• Authors of publication: Man, Wai-Lun; Chen, Gui; Yiu, Shek-Man; Shek, Lam; Wong, Wai-Yeung; Wong, Wing-Tak; Lau, Tai-Chu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 46
• Pages of publication: 11163 - 11170
• a: 12.174 ± 0.001 Å
• b: 20.3147 ± 0.0016 Å
• c: 22.373 ± 0.0018 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5533.1 ± 0.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0846
• Residual factor for significantly intense reflections: 0.0486
• Weighted residual factors for significantly intense reflections: 0.1108
• Weighted residual factors for all reflections included in the refinement: 0.1272
• Goodness-of-fit parameter for all reflections included in the refinement: 1.098
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No