Information card for entry 7026519

Structure parameters

• Common name: (PPh3)2PtSeDbb_CH2Cl2
• Chemical name: selenaplatinacycle
• Formula: C53 H42 Cl2 P2 Pt Se
• Calculated formula: C53 H42 Cl2 P2 Pt Se
• Title of publication: Thermal reaction of a (hydrido)(selenolato)platinum(II) complex having a dibenzobarrelenyl group leading to three cyclometalations.
• Authors of publication: Ishii, Akihiko; Yamaguchi, Yuki; Nakata, Norio
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 27
• Pages of publication: 6181 - 6183
• a: 12.9249 ± 0.0005 Å
• b: 13.1578 ± 0.0005 Å
• c: 15.7079 ± 0.0006 Å
• α: 74.734 ± 0.001°
• β: 69.459 ± 0.001°
• γ: 61.944 ± 0.001°
• Cell volume: 2191.88 ± 0.15 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 103 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0318
• Residual factor for significantly intense reflections: 0.0286
• Weighted residual factors for significantly intense reflections: 0.0691
• Weighted residual factors for all reflections included in the refinement: 0.0706
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No