Information card for entry 7026715

Structure parameters

• Common name: Trichloro-1kappa$2!,2kappa-2-eta$3!-allyl-mu(tert-butyl-(1,3- di-tert-butyl-4-(2-diphenylphosphanylphenoxy)-(1,3,2,4) diazadiphosphetidin-2-yl)amine-1kappaP',P'':2kappaP)dipalladum(ii)
• Chemical name: Trichloro-1κ^2^,2κ-2-η^3^-allyl-μ(tert-butyl-[1,3-di- tert-butyl-4-(2-diphenylphosphanylphenoxy)-[1,3,2,4] diazadiphosphetidin-2-yl]amine-1κP',P":2κP)dipalladum(II)
• Formula: C33 H47 Cl3 N3 O P3 Pd2
• Calculated formula: C33 H47 Cl3 N3 O P3 Pd2
• Title of publication: Transition metal chemistry of cyclodiphosphanes containing phosphine and amide-phosphine functionalities: formation of a stable dipalladium(II) complex containing a Pd-P σ-bond.
• Authors of publication: Balakrishna, Maravanji S.; Venkateswaran, Ramalingam; Mague, Joel T.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2010
• Journal volume: 39
• Journal issue: 46
• Pages of publication: 11149 - 11162
• a: 10.3506 ± 0.0013 Å
• b: 14.9616 ± 0.0018 Å
• c: 24.149 ± 0.003 Å
• α: 90°
• β: 91.218 ± 0.002°
• γ: 90°
• Cell volume: 3738.9 ± 0.8 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0432
• Residual factor for significantly intense reflections: 0.0373
• Weighted residual factors for significantly intense reflections: 0.0966
• Weighted residual factors for all reflections included in the refinement: 0.1006
• Goodness-of-fit parameter for all reflections included in the refinement: 1.07
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No