Information card for entry 7026997

Structure parameters

• Formula: C46 H27 Cl2 F39 P Rh
• Calculated formula: C46 H27 Cl2 F39 P Rh
• SMILES: [Rh]1234(Cl)(Cl)([P](c5ccc(cc5)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)(c5ccc(cc5)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c5ccc(cc5)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
• Title of publication: Platinum group metal complexes of arylphosphine ligands containing perfluoroalkyl ponytails; crystal structures of [RhCl2(η5-C5Me5){P(C6H4C6F13-4)3}] and cis- and trans-[PtCl2{P(C6H4C6F13-4)3}2]
• Authors of publication: Fawcett, John; G. Hope, Eric; Kemmitt, Raymond D. W.; Paige, Danny R.; Russell, David R.; M. Stuart, Alison; Stuart, M.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 22
• Pages of publication: 3751
• a: 7.911 ± 0.003 Å
• b: 45.183 ± 0.013 Å
• c: 15.33 ± 0.002 Å
• α: 90°
• β: 93.43 ± 0.01°
• γ: 90°
• Cell volume: 5470 ± 3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1588
• Residual factor for significantly intense reflections: 0.0787
• Weighted residual factors for all reflections: 0.1828
• Weighted residual factors for significantly intense reflections: 0.1679
• Goodness-of-fit parameter for all reflections: 1.003
• Goodness-of-fit parameter for significantly intense reflections: 1.39
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No