Information card for entry 7027187

Structure parameters

• Formula: C64 H46 Cl3 O9 P3 Pt3 Rh2
• Calculated formula: C64 H46 Cl3 O9 P3 Pt3 Rh2
• SMILES: [Pt]123([Pt]4567([Pt]89([Rh]%1014([Rh]258(C3=O)(C7=O)(C#[O])C%10=O)(C9=O)(C6=O)C#[O])([P](c1ccccc1)(c1ccccc1)c1ccccc1)C#[O])[P](c1ccccc1)(c1ccccc1)c1ccccc1)([P](c1ccccc1)(c1ccccc1)c1ccccc1)C#[O].ClC(Cl)Cl
• Title of publication: Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh3)3] and [Rh2Pt2(μ-CO)3(CO)4(PPh3)3]; crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh3)3] †
• Authors of publication: Dolgushin, Fiodor M.; Grachova, Elena V.; Heaton, Brian T.; Iggo, Jonathan A.; Koshevoy, Igor O.; Podkorytov, Ivan S.; Smawfield, Daniel J.; Tunik, Sergey P.; Whyman, Robin; Yanovskii, Aleksandr I.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 10
• Pages of publication: 1609
• a: 34.12 ± 0.012 Å
• b: 24.245 ± 0.007 Å
• c: 24.169 ± 0.008 Å
• α: 90°
• β: 134.21 ± 0.02°
• γ: 90°
• Cell volume: 14331 ± 9 ų
• Cell temperature: 143 ± 2 K
• Ambient diffraction temperature: 143 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.132
• Residual factor for significantly intense reflections: 0.0621
• Weighted residual factors for all reflections: 0.1684
• Weighted residual factors for significantly intense reflections: 0.1354
• Goodness-of-fit parameter for all reflections: 0.96
• Goodness-of-fit parameter for significantly intense reflections: 1.096
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No