Information card for entry 7027249

Structure parameters

• Common name: [{Au[mu-N(SiMe3)C(Ph)C(SiMe3)2]}2]
• Formula: C34 H64 Au2 N2 Si6
• Calculated formula: C34 H64 Au2 N2 Si6
• SMILES: [Au]12[Au]([N](=C(C2([Si](C)(C)C)[Si](C)(C)C)c2ccccc2)[Si](C)(C)C)C(C(=[N]1[Si](C)(C)C)c1ccccc1)([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Spectroscopic and electronic properties of 1-azaallylmetal(I) (M = Cu or Au) complexes; molecular structure of [{Au[μ-N(R)C(Ph)CR2]}2] (R = SiMe3)
• Authors of publication: Hitchcock, Peter B.; Lappert, Michael F.; Layh, Marcus; Klein, Axel
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 9
• Pages of publication: 1455
• a: 10.087 ± 0.007 Å
• b: 17.602 ± 0.005 Å
• c: 13.092 ± 0.003 Å
• α: 90°
• β: 108.78 ± 0.03°
• γ: 90°
• Cell volume: 2200.8 ± 1.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0578
• Residual factor for significantly intense reflections: 0.034
• Weighted residual factors for all reflections: 0.0717
• Weighted residual factors for significantly intense reflections: 0.0639
• Goodness-of-fit parameter for all reflections: 0.997
• Goodness-of-fit parameter for significantly intense reflections: 1.029
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No