Bis(isodiazene) and related complexes of molybdenum(VI). Syntheses and structures of [Mo(OTf )2(NNPh2)2(py)2], [MoCl(OTf )(NNPh2){NC5H3(CH2C(O)Ph2)2-2,6}], [{MoCl(NNPh2)2(μ-Cl)(NH2But)}2] and [MoTp′Cl(NNPh2)2] [OTf = O3SCF3, Tp′ = tris(3,5-dimethylpyrazolyl)hydroborate]
Authors of publication
Dilworth, Jonathan R.; Gibson, Vernon C.; Davies, Nicola; Redshaw, Carl; White, Andrew P.; Williams, David J.
Journal of publication
Journal of the Chemical Society, Dalton Transactions
Year of publication
1999
Journal issue
16
Pages of publication
2695
a
12.9 ± 0.002 Å
b
14.588 ± 0.003 Å
c
14.795 ± 0.003 Å
α
119.41 ± 0.02°
β
91.321 ± 0.014°
γ
95.5 ± 0.02°
Cell volume
2406.3 ± 0.9 Å3
Cell temperature
223 ± 2 K
Ambient diffraction temperature
223 ± 2 K
Number of distinct elements
8
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0938
Residual factor for significantly intense reflections
0.0628
Weighted residual factors for all reflections
0.1705
Weighted residual factors for significantly intense reflections
0.1494
Goodness-of-fit parameter for all reflections
1.056
Goodness-of-fit parameter for significantly intense reflections
