Information card for entry 7027535

Structure parameters

• Chemical name: bis{tri-o-tolylsilanethiolato(tri-phenylphosphine)silver(I)}bis(toluene)
• Formula: C46 H44 Ag P S Si
• Calculated formula: C46 H44 Ag P S Si
• Title of publication: Synthesis, X-ray and solid state NMR studies on silver(I) silanethiolates. Crystal structure of bis[(triphenylphosphine)(tri-o-tolylsilanethiolato)silver(I)]‒toluene(1/2), [{Ag[SSi(C6H4Me-o)3](PPh3)}2]·2C6H5Me †
• Authors of publication: Chojnacki, Jaroslaw; Becker, Barbara; Konitz, Atoni; Potrzebowski, Marek J.; Wojnowski, Wieslaw
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 17
• Pages of publication: 3063
• a: 12.824 ± 0.003 Å
• b: 13.667 ± 0.003 Å
• c: 14.524 ± 0.003 Å
• α: 115.15 ± 0.03°
• β: 99.76 ± 0.03°
• γ: 107.71 ± 0.03°
• Cell volume: 2059 ± 1.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0927
• Residual factor for significantly intense reflections: 0.0267
• Weighted residual factors for significantly intense reflections: 0.0716
• Weighted residual factors for all reflections included in the refinement: 0.0899
• Goodness-of-fit parameter for all reflections included in the refinement: 0.998
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No