Information card for entry 7027550

Structure parameters

• Formula: C104 H96 Cl2 O8 P8 Pt4 S4 Zn
• Calculated formula: C104 H96 Cl2 O8 P8 Pt4 S4 Zn
• SMILES: c1(ccccc1)[P]1(c2ccccc2)CC[P](c2ccccc2)(c2ccccc2)[Pt]21[S]1[Zn]3([S]4[Pt]5([P](c6ccccc6)(c6ccccc6)CC[P]5(c5ccccc5)c5ccccc5)[S]3[Pt]34[P](c4ccccc4)(c4ccccc4)CC[P]3(c3ccccc3)c3ccccc3)[S]2[Pt]21[P](c1ccccc1)(c1ccccc1)CC[P]2(c1ccccc1)c1ccccc1.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• Title of publication: Extending knowledge on the nucleophilicity of the {Pt2S2} core: Ph2PCH2CH2PPh2 as an alternative terminal ligand in [L2Pt(μ-S)2PtL2] metalloligands †
• Authors of publication: Capdevila, Mercè; Carrasco, Yolanda; Clegg, William; Coxall, Robert A.; González-Duarte, Pilar; Lledós, Agustí; Antonio Ramírez, José; Ramírez, Antonio
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 17
• Pages of publication: 3103
• a: 13.649 ± 0.008 Å
• b: 33.654 ± 0.019 Å
• c: 23.209 ± 0.012 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 10661 ± 10 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 8
• Space group number: 20
• Hermann-Mauguin space group symbol: C 2 2 21
• Hall space group symbol: C 2c 2
• Residual factor for all reflections: 0.1239
• Residual factor for significantly intense reflections: 0.1052
• Weighted residual factors for significantly intense reflections: 0.2223
• Weighted residual factors for all reflections included in the refinement: 0.2295
• Goodness-of-fit parameter for all reflections included in the refinement: 1.219
• Diffraction radiation wavelength: 0.6865 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No