Information card for entry 7027596

Structure parameters

• Common name: [V2(H)2{SiMe3N(CH2CH2NSiMe3)2}2]
• Formula: C26 H72 N6 Si6 V2
• Calculated formula: C26 H72 N6 Si6 V2
• SMILES: [V]123([N](CCN3[Si](C)(C)C)(CCN1[Si](C)(C)C)[Si](C)(C)C)[H][V]13([H]2)N(CC[N]1(CCN3[Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
• Title of publication: Vanadium(III) complexes incorporating the silylamino(disilylamido) ligand [(Me3Si)N{CH2CH2N(SiMe3)}2]2− [N{N″}2]2−. Synthesis and crystal structure of the dimeric, non-metallocene vanadium(III) hydride [{V(N{N″}2)}2(μ-H)2]
• Authors of publication: Clancy, Gerald P.; Clark, Howard C. S.; Clentsmith, Guy K. B.; Cloke, F. Geoffrey N.; Hitchcock, Peter B.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 19
• Pages of publication: 3345
• a: 10.562 ± 0.005 Å
• b: 18.902 ± 0.002 Å
• c: 11.236 Å
• α: 90 ± 0.03°
• β: 113.73°
• γ: 90°
• Cell volume: 2053.5 ± 1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0698
• Residual factor for significantly intense reflections: 0.048
• Weighted residual factors for all reflections: 0.1265
• Weighted residual factors for significantly intense reflections: 0.1125
• Goodness-of-fit parameter for all reflections: 0.998
• Goodness-of-fit parameter for significantly intense reflections: 1.016
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No