Information card for entry 7027701

Structure parameters

• Formula: C27 H20 As2 Co O4 P W
• Calculated formula: C27 H20 As2 Co O4 P W
• SMILES: [W]123456([Co]7([P](c8ccccc8)(c8ccccc8)c8ccccc8)([As]1=[As]27)(C#[O])C#[O])(C#[O])(C#[O])[cH]1[cH]6[cH]5[cH]4[cH]31
• Title of publication: Synthesis, reactivity and structural characterization of some heterometallic complexes containing naked arsenic ligands †
• Authors of publication: Adams, Katherine V.; Choi, Nick; Conole, Gráinne; Davies, John E.; King, Jason D.; Mays, Martin J.; McPartlin, Mary; Raithby, Paul R.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 21
• Pages of publication: 3679
• a: 12.772 ± 0.001 Å
• b: 20.831 ± 0.002 Å
• c: 10.493 ± 0.002 Å
• α: 90.43 ± 0.01°
• β: 103.48 ± 0.01°
• γ: 90.82 ± 0.01°
• Cell volume: 2714.3 ± 0.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1131
• Residual factor for significantly intense reflections: 0.0539
• Weighted residual factors for significantly intense reflections: 0.1457
• Weighted residual factors for all reflections included in the refinement: 0.1715
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No