Information card for entry 7027800

Structure parameters

• Formula: C47 H53 Fe N O6 P2 Pd Si
• Calculated formula: C48 H39 Fe N O6 P2 Pd Si
• Title of publication: Hydrocarbyl derivatives of dppm- or dppa-bridged alkoxysilyl heterobimetallic Fe‒Pd complexes and CO insertion reactions. Crystal structures of [(OC)3{(MeO)3Si}Fe(μ-dppm)Pd(8-mq)] (dppm = Ph2PCH2PPh2), [(OC)3Fe{μ-Si(OMe)2(OMe)}(μ-dppa)PdCl] and [(OC)3Fe{μ-Si(OMe)2(OMe)}(μ-dppa)PdPh] (dppa = Ph2PNHPPh2) †
• Authors of publication: Braunstein, Pierre; Durand, Jérôme; Kickelbick, Guido; Knorr, Michael; Morise, Xavier; Pugin, Raphael; Tiripicchio, Antonio; Ugozzoli, Franco
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 23
• Pages of publication: 4175
• a: 11.562 ± 0.002 Å
• b: 21.028 ± 0.003 Å
• c: 18.837 ± 0.003 Å
• α: 90 ± 0°
• β: 97 ± 0.02°
• γ: 90 ± 0°
• Cell volume: 4545.6 ± 1.3 ų
• Cell temperature: 298 K
• Ambient diffraction temperature: 298 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.055
• Weighted residual factors for all reflections: 0.075
• Goodness-of-fit parameter for all reflections: 0.899
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: Mokapha
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No