Information card for entry 7027828

Structure parameters

• Common name: [(salen)VOV(O)(salen)][ClO4]
• Formula: C36 H36 Cl N4 O10 V2
• Calculated formula: C36 H36 Cl N4 O10 V2
• SMILES: [V]123(Oc4c(C=[N]2CC[N]3=Cc2c(O1)ccc(c2)C)cc(cc4)C)=[O][V]123(Oc4c(C=[N]2CC[N]3=Cc2c(O1)ccc(c2)C)cc(cc4)C)=O.Cl(=O)(=O)(=O)[O-]
• Title of publication: New compounds of tetradentate Schiff bases with vanadium(IV) and vanadium(V) †
• Authors of publication: Choudhary, Nosheen F.; Connelly, Neil G.; Hitchcock, Peter B.; Leigh, G. Jeffery
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 24
• Pages of publication: 4437
• a: 15.157 ± 0.005 Å
• b: 10.378 ± 0.002 Å
• c: 23.576 ± 0.005 Å
• α: 90°
• β: 93.33 ± 0.02°
• γ: 90°
• Cell volume: 3702.2 ± 1.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1362
• Residual factor for significantly intense reflections: 0.0752
• Weighted residual factors for all reflections: 0.2232
• Weighted residual factors for significantly intense reflections: 0.1796
• Goodness-of-fit parameter for all reflections: 1.026
• Goodness-of-fit parameter for significantly intense reflections: 1.12
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No