Information card for entry 7027840

Structure parameters

• Chemical name: bistriphenylphosphine-{bis(phenylethane-1,2-diol)boryl} platinum dichloromethane solvate
• Formula: C54 H50 B2 Cl4 O4 P2 Pt
• Calculated formula: C54 H48 B2 Cl4 O4 P2 Pt
• Title of publication: Platinum-catalysed 1,4-diboration of 1,3-dienes
• Authors of publication: Clegg, William; Johann, Thorsten R. F.; Marder, Todd B.; Norman, Nicholas C.; Orpen, A. Guy; Peakman, Torren M.; Quayle, Michael J.; Rice, Craig R.; Scott, Andrew J.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 9
• Pages of publication: 1431
• a: 38.311 ± 0.003 Å
• b: 12.1983 ± 0.0013 Å
• c: 11.121 ± 0.0007 Å
• α: 90°
• β: 94.53 ± 0.007°
• γ: 90°
• Cell volume: 5180.9 ± 0.8 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 5
• Hermann-Mauguin space group symbol: C 1 2 1
• Hall space group symbol: C 2y
• Residual factor for all reflections: 0.0251
• Residual factor for significantly intense reflections: 0.0219
• Weighted residual factors for all reflections: 0.0487
• Weighted residual factors for significantly intense reflections: 0.0481
• Goodness-of-fit parameter for all reflections: 0.966
• Goodness-of-fit parameter for significantly intense reflections: 1.004
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No