Information card for entry 7028048

Structure parameters

• Chemical name: cis-bis(dimethylsulfoxide-S)-cis-(chloride)(carbonyl)(μ-chloride)(μ- dimethylsulfoxide-O,S) cis-bis(chloride)-cis-(dimethylsulfoxide-S)-carbonyl-di-ruthenium(II)
• Formula: C10 H24 Cl4 O6 Ru2 S4
• Calculated formula: C10 H24 Cl4 O6 Ru2 S4
• SMILES: [Ru]1(Cl)(Cl)([Cl][Ru](Cl)([S](=O)(C)C)([S](=O)(C)C)([O]=[S]1(C)C)C#[O])([S](=O)(C)C)C#[O]
• Title of publication: The first example of a double bridged diruthenium(II) complex containing the rare bridging S,O bidentate dimethyl sulfoxide ligand which defines a stable Ru‒Cl‒Ru‒S‒O five-membered ring
• Authors of publication: Geremia, Silvano; Mestroni, Stefano; Calligaris, Mario; Alessio, Enzo
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 15
• Pages of publication: 2447
• a: 9.506 ± 0.001 Å
• b: 13.447 ± 0.001 Å
• c: 19.208 ± 0.003 Å
• α: 90°
• β: 91.19 ± 0.01°
• γ: 90°
• Cell volume: 2454.8 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1031
• Residual factor for significantly intense reflections: 0.047
• Weighted residual factors for significantly intense reflections: 0.1083
• Weighted residual factors for all reflections included in the refinement: 0.125
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No