Information card for entry 7028084

Structure parameters

• Formula: C47 H53 Cl9 N2 P2
• Calculated formula: C47 H53 Cl9 N2 P2
• Title of publication: Complexes of the (1R)-(+)-camphor azine diphosphines Z,Z-3,3′-Ph2PnC10H15N‒NC10H15PxPh2 and Z,Z-3,3′-Ph2PxC10H15N‒N C10H15PxPh2 (x = exo, n = endo) with Group 6 metal carbonyls: crystal structures of the ligands and fac-[W(CO)3(E,Z-Ph2PxC10H15 N‒NC10H15PxPh2)]
• Authors of publication: Shaw, Bernard L.; Iranpoor, Nasser; Perera, Sarath D.; Thornton-Pett, Mark; Vessey, Jonathan D.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 11
• Pages of publication: 1885
• a: 26.172 ± 0.002 Å
• b: 10.8054 ± 0.0008 Å
• c: 17.568 ± 0.002 Å
• α: 90°
• β: 93.796 ± 0.008°
• γ: 90°
• Cell volume: 4957.3 ± 0.8 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 5
• Hermann-Mauguin space group symbol: C 1 2 1
• Hall space group symbol: C 2y
• Residual factor for all reflections: 0.0642
• Residual factor for significantly intense reflections: 0.0508
• Weighted residual factors for all reflections: 0.1517
• Weighted residual factors for significantly intense reflections: 0.1454
• Goodness-of-fit parameter for all reflections: 1.138
• Goodness-of-fit parameter for significantly intense reflections: 1.239
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No