Information card for entry 7028113

Structure parameters

• Formula: C102 H264 Al4 Li4 N16 Si12
• Calculated formula: C102.504 H241.872 Al4 Li4 N15.496 Si12
• Title of publication: Reactions of the alkyltrihydroaluminate [Li(thf )2{AlH3[C(SiMe3)3]}]2. Crystal structures of [Li(tmen)2][AlH3{C(SiMe3)3}], [AlBr2{C(SiMe3)3}]·thf, [AlI2{C(SiMe3)3}]·thf, [Li(thf )2(μ-NHPh)2{AlH[C(SiMe3)3]}] and [Li(thf )4][Al(NHPh)3{C(SiMe3)3}]
• Authors of publication: Al-Juaid, Salih S.; Eaborn, Colin; Gorrell, Ian B.; Hawkes, Simon A.; Hitchcock, Peter B.; Smith, J. David
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 14
• Pages of publication: 2411
• a: 17.315 ± 0.007 Å
• b: 26.471 ± 0.009 Å
• c: 32.8 ± 0.013 Å
• α: 90°
• β: 91.16 ± 0.03°
• γ: 90°
• Cell volume: 15031 ± 10 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1571
• Residual factor for significantly intense reflections: 0.0794
• Weighted residual factors for all reflections: 0.2241
• Weighted residual factors for significantly intense reflections: 0.1778
• Goodness-of-fit parameter for all reflections: 1.023
• Goodness-of-fit parameter for significantly intense reflections: 1.136
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No