Information card for entry 7028173

Structure parameters

• Formula: C48 H88 N8 Na4 Sb4
• Calculated formula: C48 H88 N8 Na4 Sb4
• SMILES: [Sb]12N34(C5CCCCC5)[Sb]5[N]1(C1CCCCC1)[Na]16[N]7(C8CCCCC8)[Sb]8N19(C1CCCCC1)[Sb]1N8%10(C8CCCCC8)[Na]3([N]2(C2CCCCC2)[Na]7%10)[N]1(C1CCCCC1)[Na]49[N]56C1CCCCC1
• Title of publication: Co-ordination of heavier alkali metals by polyimido antimony(III) ligands; syntheses and structures of [{Sb2(NC6H11)4}2M4] (M = Li or Na), Li[{(Me2N)Sb(μ-NC6H11)2}2Sb] and M[{(C6H11NH)Sb(μ-NC6H11)2}2Sb]·2thf (M = K or Rb)
• Authors of publication: Bashall, Alan; Beswick, Michael A.; Harmer, Christopher N.; Hopkins, Alexander D.; McPartlin, Mary; Paver, Michael A.; Raithby, Paul R.; Wright, Dominic S.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 8
• Pages of publication: 1389
• a: 24.56 ± 0.004 Å
• b: 18.455 ± 0.011 Å
• c: 25.187 ± 0.005 Å
• α: 90°
• β: 91.28 ± 0.02°
• γ: 90°
• Cell volume: 11413 ± 7 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/a 1
• Hall space group symbol: -P 2yab
• Residual factor for all reflections: 0.2537
• Residual factor for significantly intense reflections: 0.0764
• Weighted residual factors for all reflections: 0.2516
• Weighted residual factors for significantly intense reflections: 0.1727
• Goodness-of-fit parameter for all reflections: 1.003
• Goodness-of-fit parameter for significantly intense reflections: 1.134
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No