Information card for entry 7028599

Structure parameters

• Chemical name: μ-{1,4-bis[bis(bis(2-(3-propenyl)phenoxy)phosphino)amino]benzene} tetrakis(chlorogold(I))
• Formula: C78 H76 Au4 Cl4 N2 O8 P4
• Calculated formula: C78 H76 Au4 Cl4 N2 O8 P4
• SMILES: [Au](Cl)[P](Oc1c(cccc1)CC=C)(Oc1c(cccc1)CC=C)N([P](Oc1c(CC=C)cccc1)([Au]Cl)Oc1c(cccc1)CC=C)c1ccc(cc1)N([P]([Au]Cl)(Oc1c(cccc1)CC=C)Oc1c(cccc1)CC=C)[P](Oc1c(cccc1)CC=C)(Oc1c(cccc1)CC=C)[Au]Cl
• Title of publication: Bisamino(diphosphonite) with dangling olefin functionalities: synthesis, metal chemistry and catalytic utility of Rh(I) and Pd(II) complexes in hydroformylation and Suzuki-Miyaura reactions.
• Authors of publication: Naik, Susmita; Kumaravel, Maruthai; Mague, Joel T.; Balakrishna, Maravanji S.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 3
• Pages of publication: 1082 - 1095
• a: 14.1051 ± 0.0008 Å
• b: 15.314 ± 0.0008 Å
• c: 18.5847 ± 0.001 Å
• α: 90°
• β: 102.948 ± 0.001°
• γ: 90°
• Cell volume: 3912.3 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0243
• Residual factor for significantly intense reflections: 0.0187
• Weighted residual factors for significantly intense reflections: 0.0375
• Weighted residual factors for all reflections included in the refinement: 0.0393
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No